Most
synthetic and cellulosic manufactured fibres are created by "extrusion"
- forcing a thick, viscous liquid (about the consistency of cold
honey) through the tiny holes of a device called a spinneret to
form continuous filaments of semi-solid polymer.
In
their initial state, the fibre-forming polymers are solids and therefore
must be first converted into a fluid state for extrusion. This is
usually achieved by melting, if the polymers are thermoplastic synthetics
(i.e., they soften and melt when heated), or by dissolving them
in a suitable solvent if they are non-thermoplastic cellulosics.
If they cannot be dissolved or melted directly, they must be chemically
treated to form soluble or thermoplastic derivatives. Recent technologies
have been developed for some specialty fibres made of polymers that
do not melt, dissolve, or form appropriate derivatives. For these
materials, the small fluid molecules are mixed and reacted to form
the otherwise intractable polymers during the extrusion process.
The Spinneret
The
spinnerets used in the production of most manufactured fibres are
similar, in principle, to a bathroom showerhead. A spinneret may
have from one to several hundred holes. The tiny openings are very
sensitive to impurities and corrosion. The liquid feeding them must
be carefully filtered (not an easy task with very viscous materials)
and, in some cases, the spinneret must be made from very expensive,
corrosion-resistant metals. Maintenance is also critical, and spinnerets
must be removed and cleaned on a regular basis to prevent clogging.
As the filaments emerge from the holes in the spinneret, the liquid
polymer is converted first to a rubbery state and then solidified.
This process of extrusion and solidification of endless filaments
is called spinning, not to be confused with the textile operation
of the same name, where short pieces of staple fibre are twisted
into yarn. There are four methods of spinning filaments of manufactured
fibres: wet, dry, melt, and gel spinning.
Wet Spinning
Wet
spinning is the oldest process. It is used for fibre-forming substances
that have been dissolved in a solvent. The spinnerets are submerged
in a chemical bath and as the filaments emerge they precipitate
from solution and solidify.
Because the solution is extruded directly into the precipitating
liquid, this process for making fibres is called wet spinning. Acrylic,
rayon, aramid, modacrylic and spandex can be produced by this process.
Dry Spinning
Dry
spinning is also used for fibre-forming substances in solution.
However, instead of precipitating the polymer by dilution or chemical
reaction, solidification is achieved by evaporating the solvent
in a stream of air or inert gas.
The filaments do not come in contact with a precipitating liquid,
eliminating the need for drying and easing solvent recovery. This
process may be used for the production of acetate, triacetate, acrylic,
modacrylic, PBI, spandex, and vinyon.
Melt Spinning
In
melt spinning, the fibre-forming substance is melted for extrusion
through the spinneret and then directly solidified by cooling. Nylon,
olefin, polyester, saran and sulfar are produced in this manner.
Melt spun fibres can be extruded from the spinneret in different
cross-sectional shapes (round, trilobal, pentagonal, octagonal,
and others). Trilobal-shaped fibres reflect more light and give
an attractive sparkle to textiles.
Pentagonal-shaped and hollow fibres, when used in carpet, show less
soil and dirt. Octagonal-shaped fibres offer glitter-free effects.
Hollow fibres trap air, creating insulation and provide loft characteristics
equal to, or better than, down.
Gel Spinning
Gel
spinning is a special process used to obtain high strength or other
special fibre properties. The polymer is not in a true liquid state
during extrusion. Not completely separated, as they would be in
a true solution, the polymer chains are bound together at various
points in liquid crystal form. This produces strong inter-chain
forces in the resulting filaments that can significantly increase
the tensile strength of the fibres. In addition, the liquid crystals
are aligned along the fibre axis by the shear forces during extrusion.
The filaments emerge with an unusually high degree of orientation
relative to each other, further enhancing strength. The process
can also be described as dry-wet spinning, since the filaments first
pass through air and then are cooled further in a liquid bath. Some
high-strength polyethylene and aramid fibres are produced by gel
spinning.
Stretching & Orientation
While extruded fibres are solidifying, or in some cases
even after they have hardened, the filaments may be drawn to impart
strength. Drawing pulls the molecular chains together and orients
them along the fibre axis, creating a considerably stronger yarn.
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